Germanium-based materials with extremely high theoretical energy capacities have gained a lot of attention recently as potential anodes for lithium ion batteries. These materials can also offer improved Li in. Lithium ion batteries (LIBs) with advanced properties, such as high energy and power. Key challenges for successful improvement of future batteries lie in achieving high energy density and capacity, excellent rate capacity, long stable cycling life, low cost, environmental fri. Germanium-based compounds, including oxides, chalcogenides, phosphides, and germanates, followed the conversion and alloying reaction mechanism. The formation of new lithium oxi. Ge alloys and their composites undergo a stepwise lithiation/delithiation process, which favors the suppression of huge volume variations and brings a moderate operating voltage. Germanium-based anode materials possess high theoretical capacity, high intrinsic electronic conductivity and fast lithium ion diffusion kinetics, making it ideal anode materials t.